| Literature DB >> 31453995 |
Cui-Juan Zhang1, Kai-Ting Lian1, Guo-Zhang Huang1, Sukhen Bala1, Zhao-Ping Ni1, Ming-Liang Tong1.
Abstract
A new Hofmann-type metal-organic framework with bent pillar ligand, [Fe(dpoda){Ag(CN)2}2] (dpoda = 2,5-di-(pyridyl)-1,3,4-oxadiazole), was synthesized. Four-, two- and one-step spin-crossover (SCO) properties were obtained by using different sizes of aromatic guests. Most importantly, hysteretic four-step SCO behaviour with the sequence of LS ↔ HS0.25LS0.75↔ HS0.5LS0.5↔ HS0.67LS0.33↔ HS is observed for the first time.Entities:
Year: 2019 PMID： 31453995 DOI： 10.1039/c9cc06017k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222