An environmentally friendly one-pot synthesis method by the ultrasound assistance for the decoration of ultrasmall Pd-Ag NPs on graphene as high active anode catalyst towards ethanol oxidation.

An environmentally friendly one-pot synthesis approach for the decoration of Pd-Ag nanoparticles with the ultrasmall size on graphene (Pd-Ag/G) by the assistance of ultrasound is proposed in this paper. This method offers exceptional advantages over other approaches such as environmentally friendly synthesis, being low temperature, reductant, surfactant free, simple, fast and one-pot synthesis. In this work, silver formate is added to the graphene suspension at 25 °C. Then, PdCl2 is added to the suspension under stirring to fabricate Pd-Ag/G. The uniform dispersity of nanoparticles with an average size of about 2-3 nm is well confirmed by transmission electron microscopy micrographs. The resultant catalyst is applied as anode electrocatalyst towards electrooxidation reaction of ethanol. The Pd-Ag/G catalyst displays exceptional catalytic activity and durability towards electro-oxidation of ethanol. According to the obtained results, it be concluded that the combination of Ag and Pd, ultrasmall and uniform distribution of Pd-Ag nanoparticles led to the improvement of electrocatalytic activity of the Pd-Ag/G catalyst.