Influence of the origin of the air mass on the background levels of atmospheric particulate matter and secondary inorganic compounds in the Madrid air basin.

This study has assessed the influence of the origin of air mass on levels of particulate matter (PM10) and chemical composition (SO42- and NO3-) in the air basin of Madrid. A data set of back-trajectories of air mass arriving to this area of study from 15 June 15 2009 to 8 July 2011 has been analyzed. Firstly, the cluster analysis statistical method has been used to group the back-trajectories into 5 sets according to the angle, direction, and speed of the air mass. Afterwards, the synoptic meteorological scenarios associated with each cluster were obtained and interpreted. Subsequently, an analysis was made on the influence of these clusters on the surface levels of particulate pollutants recorded in a regional background station ("El Atazar"), as well as in two urban background stations ("Casa de Campo" and "CIEMAT"). Finally, potential source areas of PM10, SO42-, and NO3- that contributed to the increase in their background levels in the Madrid air basin were detected by analyzing residence times of trajectories. Transport of mineral desert dust is probably the main cause of the increase of regional and urban background levels of PM10 in the Madrid air basin. In the case of SO42-, relatively high levels were registered, associated with air mass coming from Southern Europe and the Mediterranean Sea. In these regions, strong emissions of SO42- are produced due to industrial combustion and maritime traffic. Otherwise, relatively high levels of NO3- were registered during meteorological situations defined by a low baric gradient in the Iberian Peninsula. This meteorological pattern favors the accumulation of emissions from local and regional sources. Besides, the main urban centers of northeastern Europe and industrial areas located in the north African coast were also identified as potential source areas of NO3-. The statistical analysis of the back-trajectories by different methods and the comparison of the results obtained with observational data confirmed that numerous industrial areas in Europe and North Africa, as well as natural ones, such as deserts, had an influence on the regional and urban background levels of mass and chemical composition of particulate matter in the Madrid air basin, under the development of specific synoptic meteorological situations. Graphical abstract.