Fabrication of Highly Dispersed Cu-Based Oxides as Desirable NH3-SCR Catalysts via Employing CNTs To Decorate the CuAl-Layered Double Hydroxides.

In this study, three kinds of CuAl-LDO/CNT (LDO, layered double oxide) catalysts were prepared by the assembly of CNTs and CuAl-LDH (LDH, layered double hydroxides) as well as subsequently structural topological transformation. The effects of the assembly method on the surface structure property and the DeNOx performance of the prepared samples were systematically investigated. It was found that three CuAl-LDO/CNT catalysts showed preferable NH3-SCR catalytic performance compared with CuAl-LDO where the catalyst CuAl-LDO/CNTs(I) exhibited optimum NOx conversion (>80%) and N2 selectivity (>90%) within 180-300 °C. Such fine catalytic performance can be attributed to the proper surface acidity and redox ability of the catalyst, which might be correlated with the high dispersion of Cu-based active centers caused by the induced nucleation and effective separation action of LDH by carbon nanotubes. In addition, the outstanding H2O and SO2 resistance of the CuAl-LDO/CNTs(I) catalyst was also obtained because of the synergistic effect between CuAl-LDO and CNTs, which could greatly promote the activation and decomposition of ammonium sulfate at lower temperatures.