Literature DB >> 31407738

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides.

Xiu Wang1, Zhenhua Wang, Yasushi Nishihara.   

Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Entities:  

Year:  2019        PMID： 31407738     DOI： 10.1039/c9cc05325e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Decarbonylative Fluoroalkylation at Palladium(II): From Fundamental Organometallic Studies to Catalysis.

Authors:  Naish Lalloo; Christian A Malapit; S Maryamdokht Taimoory; Conor E Brigham; Melanie S Sanford
Journal:  J Am Chem Soc       Date:  2021-10-28       Impact factor: 15.419

2.  Bulky Di(1-adamantyl)phosphinous Acid-Ligated Pd(II) Precatalysts for Suzuki Reactions of Unreactive Aryl Chlorides.

Authors:  He-Xin Xiao; Wan-Yun Hsu; Siou-Wei Liang; Yingjie Guo; Wan-Ching Lee; I-Chung Lu; Yu-Chang Chang
Journal:  ACS Omega       Date:  2021-12-08

3.  Carbon-11 carboxylation of trialkoxysilane and trimethylsilane derivatives using [11C]CO2.

Authors:  Salvatore Bongarzone; Nicola Raucci; Igor Camargo Fontana; Federico Luzi; Antony D Gee
Journal:  Chem Commun (Camb)       Date:  2020-03-25       Impact factor: 6.222

4.  Silicon compounds in carbon-11 radiochemistry: present use and future perspectives.

Authors:  Federico Luzi; Antony D Gee; Salvatore Bongarzone
Journal:  Org Biomol Chem       Date:  2021-07-28       Impact factor: 3.876
  4 in total

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