Literature DB >> 31395758

Response to Comment on "Observation of alkaline earth complexes M(CO)8 (M = Ca, Sr, or Ba) that mimic transition metals".

Lili Zhao1, Sudip Pan1,2, Mingfei Zhou3, Gernot Frenking4,2.   

Abstract

Landis et al claim in their comment that Ca does not bind like a transition metal in Ca(CO)8 We reject their statement, which is based on a misconception of bonding models and misleading application and interpretation of quantum chemical methods for analyzing chemical bonds.
Copyright © 2019, American Association for the Advancement of Science.

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Year:  2019        PMID： 31395758     DOI： 10.1126/science.aay5021

Source DB:  PubMed          Journal:  Science        ISSN： 0036-8075            Impact factor:   47.728


  8 in total

1.  Synthesis and characterization of crystalline niobium and tantalum carbonyl complexes at room temperature.

Authors:  W Unkrig; M Schmitt; D Kratzert; D Himmel; I Krossing
Journal:  Nat Chem       Date:  2020-06-22       Impact factor: 24.427

2.  Energy Decomposition Analysis Coupled with Natural Orbitals for Chemical Valence and Nucleus-Independent Chemical Shift Analysis of Bonding, Stability, and Aromaticity of Functionalized Fulvenes: A Bonding Insight.

Authors:  Sai Manoj N V T Gorantla; Kartik Chandra Mondal
Journal:  ACS Omega       Date:  2021-07-06

3.  The Valence Orbitals of the Alkaline-Earth Atoms.

Authors:  Israel Fernández; Nicole Holzmann; Gernot Frenking
Journal:  Chemistry       Date:  2020-09-29       Impact factor: 5.236

4.  Bonding and stability of donor ligand-supported heavier analogues of cyanogen halides (L')PSi(X)(L).

Authors:  Sai Manoj N V T Gorantla; Maria Francis; Sudipta Roy; Kartik Chandra Mondal
Journal:  RSC Adv       Date:  2021-02-10       Impact factor: 3.361

5.  Estimations of Fe0/-1-N2 interaction energies of iron(0)-dicarbene and its reduced analogue by EDA-NOCV analyses: crucial steps in dinitrogen activation under mild conditions.

Authors:  Sai Manoj N V T Gorantla; Kartik Chandra Mondal
Journal:  RSC Adv       Date:  2022-01-26       Impact factor: 3.361

6.  Bonding and stability of dinitrogen-bonded donor base-stabilized Si(0)/Ge(0) species [(cAACMe-Si/Ge)2(N2)]: EDA-NOCV analysis.

Authors:  Harsha S Karnamkkott; Sai Manoj N V T Gorantla; Kavita Devi; Geetika Tiwari; Kartik Chandra Mondal
Journal:  RSC Adv       Date:  2022-02-01       Impact factor: 3.361

7.  Donor-acceptor duality of the transition-metal-like B2 core in core-shell-like metallo-borospherenes La3&[B2@B17]- and La3&[B2@B18].

Authors:  Xiao-Yun Zhao; Miao Yan; Zhihong Wei; Si-Dian Li
Journal:  RSC Adv       Date:  2020-09-15       Impact factor: 4.036

Review 8.  Transition-Metal Chemistry of Alkaline-Earth Elements: The Trisbenzene Complexes M(Bz)3 (M=Sr, Ba).

Authors:  Qian Wang; Sudip Pan; Yan-Bo Wu; Guohai Deng; Jian-Hong Bian; Guanjun Wang; Lili Zhao; Mingfei Zhou; Gernot Frenking
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-17       Impact factor: 15.336
  8 in total

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