Metal-Organic Framework-Based Composite for Photocatalytic Detection of Prevalent Pollutant.

Photocatalytic properties of 2,5-furandicarboxylic acid (FDCA), a model organic molecule used for biopolymer production, are reported for the first time. Further integration of FDCA into metal-organic framework (MOF) structures and subsequent silver-based photoactivation leads to the next generation of hybrids with controlled morphologies, capable of forming sensorial platforms for prevalent phenol contaminant detection. The mechanisms that allow photocatalytic functionality are driven by the charge carrier generation in the organic molecule (either in its alone or integrated form) and depend on sample's physical and chemical properties as confirmed by scanning and transmission electron microscopy, Fourier transform infrared and X-ray photoelectron spectroscopy, and X-ray diffraction, respectively. Electrochemical analysis using cyclic voltammetry confirmed high sensitivity for p-nitrophenol (p-NP) detection as dictated by the selective electron migration at a user-controlled electrode interface. Considering the wide usage of p-NP and its increased discharge shown to lead to harmful effects on both the environment and biosystems, this new detection method is envisioned to allow effective control and regulation of such compound release, all under low-cost and environmentally friendly conditions.