Mussel-inspired immobilization of silver nanoparticles toward sponge for rapid swabbing extraction and SERS detection of trace inorganic explosives.

It is fairly crucial to detect inorganic explosives through a sensitive and fast method in the field of public safety, nevertheless, the high non-volatility and stability characteristics severely confine their accurate on-site detection from a real-world surface. In this work, an efficient, simple and cost effective method was developed to fabricate uniform silver nanoparticles (AgNPs) immobilized on polyurethane (PU) sponge through the in-situ reduction of polydopamine (PDA) based on mussel-inspired surface chemistry, in virtue of a large quantities catechol and amine functional groups. The formed PU@PDA@Ag sponges exhibited high SERS sensitivity, uniformity and reproducibility to 4-Aminothiophenol (4-ATP) probe molecule, and the limit of detection was calculated to be about 0.02 nmol L-1. Moreover, these PU@PDA@Ag sponges could be served as excellent flexible SERS substrates to rapidly detect trace inorganic explosives with high collection efficiency via swabbing extraction. The detection limit for perchlorates (ClO4-), chlorates (ClO3-) and nitrates (NO3-) were approximately down to 0.13, 0.13 and 0.11 ng respectively. These flexible substrates not only could drastically increase the sample collection efficiency, but also enhance analytical sensitivity and reliability for inorganic explosive, and would have a great potential application in the future homeland security fields.