Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand.

Literature DB >> 31325369

Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand.

Huatian Shi¹, Jianhui Xie², William W Y Lam³, Wai-Lun Man⁴, Chi-Keung Mak¹, Shek-Man Yiu¹, Hung Kay Lee⁵, Tai-Chu Lau¹.

Abstract

The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV (TAML)(N-Mes)]- (1), are reported. Compound 1 is oxidized by [(p-BrC6 H4 )3 N]+. [SbCl6 ]- and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions.

Entities: Chemical

Keywords: coordination chemistry; hydrogen atom transfer; imido transfer; manganese; one-electron oxidation

Year: 2019 PMID： 31325369 DOI： 10.1002/chem.201902405

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

Keyword Cloud
Cited

4 in total

1. Ligand Redox Noninnocence in [Co^III(TAML)]^0/- Complexes Affects Nitrene Formation.

Authors: Nicolaas P van Leest; Martijn A Tepaske; Jean-Pierre H Oudsen; Bas Venderbosch; Niels R Rietdijk; Maxime A Siegler; Moniek Tromp; Jarl Ivar van der Vlugt; Bas de Bruin
Journal: J Am Chem Soc Date: 2019-12-30 Impact factor: 15.419

2. Nitrogen Atom Transfer Catalysis by Metallonitrene C-H Insertion: Photocatalytic Amidation of Aldehydes.

Authors: Till Schmidt-Räntsch; Hendrik Verplancke; Jonas N Lienert; Serhiy Demeshko; Matthias Otte; Gerard P Van Trieste; Kaleb A Reid; Joseph H Reibenspies; David C Powers; Max C Holthausen; Sven Schneider
Journal: Angew Chem Int Ed Engl Date: 2022-01-14 Impact factor: 16.823

3. Electronically Asynchronous Transition States for C-N Bond Formation by Electrophilic [Co^III(TAML)]-Nitrene Radical Complexes Involving Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered Spin Shuttle.

Authors: Nicolaas P van Leest; Martijn A Tepaske; Bas Venderbosch; Jean-Pierre H Oudsen; Moniek Tromp; Jarl Ivar van der Vlugt; Bas de Bruin
Journal: ACS Catal Date: 2020-06-12 Impact factor: 13.700

4. Catalytic Chemoselective Sulfimidation with an Electrophilic [Co^III (TAML)]^- -Nitrene Radical Complex*.

Authors: Nicolaas P van Leest; Jarl Ivar van der Vlugt; Bas de Bruin
Journal: Chemistry Date: 2020-11-19 Impact factor: 5.236

4 in total

Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand.

1. Ligand Redox Noninnocence in [CoIII(TAML)]0/- Complexes Affects Nitrene Formation.

2. Nitrogen Atom Transfer Catalysis by Metallonitrene C-H Insertion: Photocatalytic Amidation of Aldehydes.

3. Electronically Asynchronous Transition States for C-N Bond Formation by Electrophilic [CoIII(TAML)]-Nitrene Radical Complexes Involving Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered Spin Shuttle.

4. Catalytic Chemoselective Sulfimidation with an Electrophilic [CoIII (TAML)]- -Nitrene Radical Complex*.

1. Ligand Redox Noninnocence in [Co^III(TAML)]^0/- Complexes Affects Nitrene Formation.

3. Electronically Asynchronous Transition States for C-N Bond Formation by Electrophilic [Co^III(TAML)]-Nitrene Radical Complexes Involving Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered Spin Shuttle.

4. Catalytic Chemoselective Sulfimidation with an Electrophilic [Co^III (TAML)]^- -Nitrene Radical Complex*.