Literature DB >> 31309945

Electrochemical synthesis of 1,2-diketones from alkynes under transition-metal-catalyst-free conditions.

Jie Zhou1, Xiang-Zhang Tao, Jian-Jun Dai, Chen-Guang Li, Jun Xu, Hong-Mei Xu, Hua-Jian Xu.   

Abstract

We report an electrochemical protocol for the direct oxidation of internal alkynes in air to provide 1,2-diketones. A variety of functional groups and heterocycle-containing substrates can be tolerated well under mild conditions.

Entities:  

Year:  2019        PMID： 31309945     DOI： 10.1039/c9cc03996a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  I2-Catalyzed Carbonylation of α-Methylene Ketones to Synthesize 1,2-Diaryl Diketones and Antiviral Quinoxalines in One Pot.

Authors:  Lingkai Kong; Jieru Meng; Wenyue Tian; Jiazheng Liu; Xueping Hu; Zhi-Hong Jiang; Wei Zhang; Yanzhong Li; Li-Ping Bai
Journal:  ACS Omega       Date:  2021-12-21

2.  Investigation on the Synthesis, Application and Structural Features of Heteroaryl 1,2-Diketones.

Authors:  Robert J Wehrle; Alexander Rosen; Thu Vu Nguyen; Kalyn Koons; Eric Jump; Mason Bullard; Natalie Wehrle; Adam Stockfish; Patrick M Hare; Abdurrahman Atesin; Tülay A Ateşin; Lili Ma
Journal:  ACS Omega       Date:  2022-07-20
  2 in total

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