Kais Dhbaibi1,2, Ludovic Favereau1, Jeanne Crassous1. 1. ISCR (Institut des Sciences Chimiques de Rennes), UMR6226, CNRS , Université Rennes , F-35000 Rennes , France. 2. Faculty of Science of Gabès , University of Gabés , Zrig , 6072 Gabès Tunisia.
Abstract
In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-group elements. Enantioenriched helicenic derivatives containing main-group elements B, Si, N, and P, either incorporated within the helical backbone or grafted to it, will be thoroughly presented. We will describe their synthesis, resolution, and asymmetric synthesis, their structural features, electronic and chiroptical properties, and emission, together with other photochemical properties and applications.
In this review, we discuss the rich chemistry of helicenes and n>an class="Chemical">helicenoids containing main-group elements. Enantioenriched helicenic derivatives containing main-group elements B, Si, N, and P, either incorporated within the helical backbone or grafted to it, will be thoroughly presented. We will describe their synthesis, resolution, and asymmetric synthesis, their structural features, electronic and chiroptical properties, and emission, together with other photochemical properties and applications.
Authors: Mahendra K Sharma; Sebastian Blomeyer; Timo Glodde; Beate Neumann; Hans-Georg Stammler; Alexander Hinz; Maurice van Gastel; Rajendra S Ghadwal Journal: Chem Sci Date: 2020-01-06 Impact factor: 9.825