Literature DB >> 31292569

Diborane heterolysis and P(v) reduction by Ph3P[double bond, length as m-dash]O coordination to magnesium.

Anne-Frédérique Pécharman1, Nasir A Rajabi1, Michael S Hill1, Claire L McMullin1, Mary F Mahon1.   

Abstract

Reaction of a magnesium diboranate complex with triphenylphosphine oxide provides a terminal magnesium boryl, which is itself a potent reagent for the deoxygenative reduction of Ph3PO. Computational analysis with density functional theory (DFT) indicates that B-B bond activation results from initial coordination of the P[double bond, length as m-dash]O bond of the phosphine oxide to magnesium.

Entities:  

Year:  2019        PMID： 31292569     DOI： 10.1039/c9cc04294f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  B-B Bond Nucleophilicity in a Tetraaryl μ-Hydridodiborane(4) Anion.

Authors:  Timo Trageser; Michael Bolte; Hans-Wolfram Lerner; Matthias Wagner
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-19       Impact factor: 15.336

2.  A Stable Calcium Alumanyl.

Authors:  Ryan J Schwamm; Martyn P Coles; Michael S Hill; Mary F Mahon; Claire L McMullin; Nasir A Rajabi; Andrew S S Wilson
Journal:  Angew Chem Weinheim Bergstr Ger       Date:  2020-01-30

3.  A (μ-hydrido)diborane(4) anion and its coordination chemistry with coinage metals.

Authors:  Xiaofeng Mao; Jie Zhang; Zhenpin Lu; Zuowei Xie
Journal:  Chem Sci       Date:  2022-02-11       Impact factor: 9.825

4.  A Stable Calcium Alumanyl.

Authors:  Ryan J Schwamm; Martyn P Coles; Michael S Hill; Mary F Mahon; Claire L McMullin; Nasir A Rajabi; Andrew S S Wilson
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-30       Impact factor: 15.336
  4 in total

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