Literature DB >> 31286448

Gas-Phase Reactivity of Carbonate Ions with Sulfur Dioxide: an Experimental Study of Clusters Reactions.

Anna Troiani1, Chiara Salvitti2, Giulia de Petris3.   

Abstract

The reactivity of carbonate cluster ions with sulfur dioxide has been investigated in the gas phase by mass spectrometric techniques. SO2 promotes the displacement of carbon dioxide from carbonate clusters through a stepwise mechanism, leading to the quantitative conversion of the carbonate aggregates into the corresponding sulfite cluster ions. The kinetic study of the reactions of positive, negative, singly, and doubly charged ions reveals very fast and efficient processes for all the carbonate ions.

Entities:  

Keywords:  Carbonates; Cluster reactivity; Ion-molecule reactions; Sulfur dioxide

Year:  2019        PMID： 31286448     DOI： 10.1007/s13361-019-02228-0

Source DB:  PubMed          Journal:  J Am Soc Mass Spectrom        ISSN： 1044-0305            Impact factor:   3.109


  27 in total

1.  Direct Experimental Evidence for the H(2)O(+)O(2)(-) Charge Transfer Complex: Crucial Support to Atmospheric Photonucleation Theory.

Authors: 
Journal:  Angew Chem Int Ed Engl       Date:  2000-01       Impact factor: 15.336

2.  Gas-phase catalysis by atomic and cluster metal ions: the ultimate single-site catalysts.

Authors:  Diethard K Böhme; Helmut Schwarz
Journal:  Angew Chem Int Ed Engl       Date:  2005-04-15       Impact factor: 15.336

3.  Reactions at surfaces: from atoms to complexity (Nobel Lecture).

Authors:  Gerhard Ertl
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

4.  The oxidation of sulfur dioxide by single and double oxygen transfer paths.

Authors:  Anna Troiani; Marzio Rosi; Chiara Salvitti; Giulia de Petris
Journal:  Chemphyschem       Date:  2014-06-20       Impact factor: 3.102

5.  Ionization of ozone/chlorofluorocarbon mixtures in atmospheric gases: formation and remarkable dissociation of

Authors: 
Journal:  Chemistry       Date:  2000-07-14       Impact factor: 5.236

6.  Double C-H activation of ethane by metal-free SO2*+ radical cations.

Authors:  Giulia de Petris; Antonella Cartoni; Anna Troiani; Vincenzo Barone; Paola Cimino; Giancarlo Angelini; Ornella Ursini
Journal:  Chemistry       Date:  2010-06-01       Impact factor: 5.236

7.  Reactive collisions of sulfur dioxide with molten carbonates.

Authors:  Thomas Krebs; Gilbert M Nathanson
Journal:  Proc Natl Acad Sci U S A       Date:  2010-02-01       Impact factor: 11.205

8.  Methane activation by metal-free radical cations: experimental insight into the reaction intermediate.

Authors:  Giulia de Petris; Anna Troiani; Marzio Rosi; Giancarlo Angelini; Ornella Ursini
Journal:  Chemistry       Date:  2009       Impact factor: 5.236

9.  Mineral dust photochemistry induces nucleation events in the presence of SO2.

Authors:  Yoan Dupart; Stephanie M King; Bettina Nekat; Andreas Nowak; Alfred Wiedensohler; Hartmut Herrmann; Gregory David; Benjamin Thomas; Alain Miffre; Patrick Rairoux; Barbara D'Anna; Christian George
Journal:  Proc Natl Acad Sci U S A       Date:  2012-12-03       Impact factor: 11.205

10.  Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions.

Authors:  Jilai Li; Shaodong Zhou; Jun Zhang; Maria Schlangen; Dandamudi Usharani; Sason Shaik; Helmut Schwarz
Journal:  J Am Chem Soc       Date:  2016-08-23       Impact factor: 15.419
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  2 in total

1.  Intracluster Sulphur Dioxide Oxidation by Sodium Chlorite Anions: A Mass Spectrometric Study.

Authors:  Chiara Salvitti; Federico Pepi; Anna Troiani; Giulia de Petris
Journal:  Molecules       Date:  2021-11-24       Impact factor: 4.411

2.  Free N-heterocyclic carbenes from Brønsted acidic ionic liquids: Direct detection by electrospray ionization mass spectrometry.

Authors:  Chiara Salvitti; Federico Pepi; Marta Managò; Martina Bortolami; Cinzia Michenzi; Isabella Chiarotto; Anna Troiani; Giulia de Petris
Journal:  Rapid Commun Mass Spectrom       Date:  2022-09-15       Impact factor: 2.586
  2 in total

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