Literature DB >> 31286207

A new EPR dosimeter based on glutamic acid for radiation processing application.

W B Beshir1, Yasser S Soliman2, A A Abdel-Fattah1, Ramy Amer Fahim1.   

Abstract

L-Glutamic acid (L-GA) pellets (3.8 mm × 4 mm) and powder dosimeters were studied in the dose range of 0.1-150 kGy using the electron paramagnetic resonance (EPR) technique. The EPR spectra of irradiated L-GA pellets showed an EPR signal with eight lines, and the intensity of the signal increased with an increase of absorbed dose. The results obtained in terms of the energy-absorption coefficients suggest a similar performance of the L-GA pellets as compared to alanine pellets. The value of the temperature coefficient for the L-GA pellets during irradiation was around - 0.08%/°C which is lower than that reported for alanine dosimeter, 0.14%/°C. The influence of humidity on the pellet response was found to be negligible; i.e., the increase in response was only about 2% for a relative humidity of up to 94%. The response of L-GA powder reached stability 4 h after irradiation and continued to be stable until 47 days after irradiation. In contrast, the response of the L-GA pellet dosimeter reached stability 22 h after irradiation and continued to be stable until 8 days after irradiation. For routine applications, the L-GA pellet dosimeter should be analyzed during the stable period after irradiation, to minimize the uncertainties in dose assessment. The overall two-sigma uncertainties in absorbed dose estimation were 5.1% and 3.9% for the dose ranges of 0.1-15 kGy and 15-150 kGy, respectively. It is concluded that L-GA pellets represent a promising dosimeter material for quantification of radiation doses in food irradiation, medical sterilization and polymer modification.

Entities:  

Keywords:  EPR spectroscopy; Electron paramagnetic resonance; L-Glutamic acid; Pellet dosimeter; Radiation dosimetry

Mesh:

Substances:

Year:  2019        PMID: 31286207     DOI: 10.1007/s00411-019-00808-y

Source DB:  PubMed          Journal:  Radiat Environ Biophys        ISSN: 0301-634X            Impact factor:   1.925


  11 in total

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4.  New materials for ESR dosimetry.

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7.  EPR dosimetric properties of 2-methylalanine: EPR, ENDOR and FT-EPR investigations.

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8.  Structure and behaviour of the free radicals generated in gamma irradiated amino acid and iminodiacetic acid derivatives.

Authors:  Semsettin Osmanoğlu; Murat Aydın; Y Emre Osmanoğlu; I Yeşim Dicle; M Halim Başkan
Journal:  Spectrochim Acta A Mol Biomol Spectrosc       Date:  2011-02-18       Impact factor: 4.098

9.  The effects of dose and radiation quality on the shape and power saturation of the EPR signal in alanine.

Authors:  B Ciesielski; L Wielopolski
Journal:  Radiat Res       Date:  1994-10       Impact factor: 2.841

10.  Monosodium glutamate for accidental, retrospective, and medical dosimetry using electron spin resonance.

Authors:  Eder J Guidelli; Iara S Lima; Oswaldo Baffa
Journal:  Radiat Environ Biophys       Date:  2018-09-21       Impact factor: 1.925

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