The net greenhouse gas benefits of wind turbines compared to their fossil energy counterparts depend on location-specific wind climatology and the turbines' technological characteristics. Assessing the environmental impact of individual wind parks requires a universal but location-dependent method. Here, the greenhouse gas payback time for 4161 wind turbine locations in northwestern Europe was determined as a function of (i) turbine size and (ii) spatial and temporal variability in wind speed. A high-resolution wind atlas (hourly wind speed data between 1979 and 2013 on a 2.5 by 2.5 km grid) was combined with a regression model predicting the wind turbines' life cycle greenhouse gas emissions from turbine size. The greenhouse gas payback time of wind turbines in northwestern Europe varied between 1.8 and 22.5 months, averaging 5.3 months. The spatiotemporal variability in wind climatology has a particularly large influence on the payback time, while the variability in turbine size is of lesser importance. Applying lower-resolution wind speed data (daily on a 30 by 30 km grid) approximated the high-resolution results. These findings imply that forecasting location-specific greenhouse gas payback times of wind turbines globally is well within reach with the availability of a high-resolution wind climatology in combination with technological information.
The net greenhouse gas benefits of wind turbines compared to their fossil energy counterparts depend on location-specific wind climatology and the turbines' technological characteristics. Assessing the environmental impact of individual wind parks requires a universal but location-dependent method. Here, the greenhouse gas payback time for 4161 wind turbine locations in northwestern Europe was determined as a function of (i) turbine size and (ii) spatial and temporal variability in wind speed. A high-resolution wind atlas (hourly wind speed data between 1979 and 2013 on a 2.5 by 2.5 km grid) was combined with a regression model predicting the wind turbines' life cycle greenhouse gas emissions from turbine size. The greenhouse gas payback time of wind turbines in northwestern Europe varied between 1.8 and 22.5 months, averaging 5.3 months. The spatiotemporal variability in wind climatology has a particularly large influence on the payback time, while the variability in turbine size is of lesser importance. Applying lower-resolution wind speed data (daily on a 30 by 30 km grid) approximated the high-resolution results. These findings imply that forecasting location-specific greenhouse gas payback times of wind turbines globally is well within reach with the availability of a high-resolution wind climatology in combination with technological information.
Wind energy is becoming increasingly important
in the world’s
electricity supply as it becomes cost competitive and the demand for
sustainable energy is rising.[1] By the end
of 2017, the cumulative capacity of all wind turbines installed globally
reached over 539 GW, meeting approximately 5% of the world’s
electricity demand.[2] It is projected that
wind could contribute 18% to 36% of the world’s electricity
production in 2050.[3,4]The environmental performance
of wind electricity is typically
determined by means of a life cycle assessment (LCA),[5] which is a systematic approach to determine the environmental
impact of a technology considering all the resources required and
related emissions during the different stages of its life cycle.[6] For wind, the environmental impact per unit of
electricity produced depends on the amount and type of materials used
to build and maintain the wind turbine as well as the electricity
produced over its life cycle.[7] Because
it is virtually impossible to perform specific LCAs for all individual
wind turbines worldwide, Caduff et al.[8] developed a regression model estimating the life cycle greenhouse
gas (GHG) emission of onshore wind turbines as a function of rotor
diameter and hub height. They found that the bigger the wind turbine,
the lower the GHG emissions per unit of electricity produced. However,
their analysis was focused on onshore turbines and did not take climatological
variations of wind speed into account.LCAs of wind turbines
are typically based on the mean wind speed
at hub height.[7−14] More recently, a comprehensive LCA study for wind electricity in
Denmark built a model to estimate a wind turbine’s life cycle
GHG emissions based on technological scaling relationships and spatiotemporal
information on wind speed data with approximately a 50 by 50 km grid
resolution.[15,16] Their study emphasized the importance
of including spatiotemporal variation of wind speed in the power calculations.
The required spatiotemporal resolution of wind speed data to obtain
reliable LCA results was, however, not analyzed in their study. To
our knowledge, a comparison of the site-specific environmental performance
of wind electricity on larger spatial scales that takes into account
detailed spatiotemporal variability in the local wind resource is
currently lacking. Moreover, it is not known which spatiotemporal
resolution actually is sufficient to capture the variability in the
wind resource in such an assessment.Here, the greenhouse gas
payback time (GPBT) of 4161 wind turbine
locations in northwestern Europe was quantified, accounting for variability
in both wind climatology and turbine technology. The GPBT is a commonly
used metric to identify the environmental performance of wind energy
compared with a fossil energy benchmark, which equals the time it
takes until the total GHG savings due to the replacement of fossil
energy by wind energy equals the GHG emissions during a turbine’s
life cycle.[17]To simulate the yearly
average power output of the individual wind
turbines high-resolution wind data for 35 years on a 2.5 by 2.5 km
grid[18] was combined with technical information
for individual wind turbines.[19] The life
cycle GHG emissions for onshore and offshore wind turbines were derived
from the turbine size with an updated regression model based on the
work by Caduff et al.[8] The importance of
using a high-resolution wind climatology data set and turbine-specific
data was assessed by analyzing the sensitivity of wind turbine GPBTs
to (i) differences in spatiotemporal detail of wind speed and (ii)
including or excluding differences in turbine size.
Materials and
Methods
Overview
The influence of time and space dependencies
in wind speed and size variations of wind turbine characteristics
on the environmental impacts was analyzed according to the steps shown
in Figure . These
steps are further explained below.
Figure 1
Schematic representation of the calculation
of the turbine-specific
greenhouse gas payback time (GPBT).
Schematic representation of the calculation
of the turbine-specific
greenhouse gas payback time (GPBT).
Greenhouse Gas Payback Time
The GPBT depends on the
total emissions during the lifetime of the wind turbine and its power
output, as well as the greenhouse gas emissions of the fossil energy
reference. The GPBT (in months) of a wind turbine is calculated aswhere GHGturbine is the cumulative
GHG emission resulting from the production and installation of the
wind turbine (kg CO2-eq/turbine), Pturbine the lifetime average electricity production of the
wind turbine (kWh/month), and GHGfossil the GHG emission
of the fossil energy benchmark (kg CO2-eq/kWh). The average
emission of natural gas-fired power plants of 0.5 kg CO2-eq/kWh was chosen as reference for the whole study area.[20]
GHG Emissions of Wind Turbine Production
To calculate
the GHG emissions, a regression model was developed that expresses
GHG emissions of a turbine during its lifetime (GHGturbine) as a function of rotor diameter (D) and hub height
(h). For this, the model from Caduff et al.[8] was modified by expanding the underlying empirical
data set[9−12,21−32] and including systematic differences in GHG emissions between onshore
and offshore turbine production.[33] A Gaussian
generalized linear model was applied using RStudio (RStudio Team,
2015), based on 28 wind turbine LCA studies of 22 on- and 6 offshore
locations. Cross-validation was performed using a leave-one-out method.[34] The best model was chosen based on the Akaike
information criterion (AIC).
Power Output
The turbine’s
power output Pturbine, at time i depends on the time-varying wind speed
at hub height u (m/s)
and the rotor diameter throughwhere μ = 0.85 is the overall efficiency
(including grid losses and machine downtime, among others),[35] μBetz the theoretical maximum
power that a wind turbine can produce (, Betz’s law),[36] ρ the air density (1.225 kg/m2), and Aturbine the swept area (m2) given
by 0.25·π·D2. A wind turbine
operates in a limited wind speed range (between cut-in and cut-out
wind speeds), below and above which no electricity is produced. Above
the rated wind speed the turbine is programmed to operate at its rated
power output until it reaches the cut-out wind speed.
Data
Wind Turbines
Wind turbines in Northwestern Europe
within the domain of 48°N to 60°N and −8°E to
+12°E were included in this study. Their location and technical
specifications were taken from The WindPower database,[19] which provides information on the turbines’
hub heights and rotor diameters. This information is used in the calculation
of the turbines’ life cycle GHG emissions (eq ) as well as their power output
(eq ). Data was available
for 4161 wind power locations within the selected domain, of which
80 are offshore and 4081 are onshore. The included technological turbine
characteristics are given in Figure .
Figure 2
Box plots show the distribution
of important technological wind
turbine characteristics for the turbines in the data set. Blue bars
are onshore turbines (n = 4061), and green bars are
offshore turbines (n = 80). The plots show the three
quartile values of the distribution, the 1.5 interquartile range represented
by the whiskers, and the data points outside this range as individual
values. The red dots represent the mean used for average turbine sizes.
Wind Speed
Wind speed data was derived
from the KNMI
North Sea Wind Atlas (KNW-Atlas).[18] This
data set contains hourly wind speed data on a 2.5 by 2.5 km grid for
all years between 1979 and 2013. The KNW-Atlas is based on ERA-Interim
reanalysis data[37] downscaled with the high-resolution,
nonhydrostatic weather forecasting model HARMONIE CY37h1.1.[38,39] It contains wind speeds at heights of 10, 20, 40, 60, 80, 100, 150,
and 200 m. The KNW-Atlas has been validated[40,41] and produces accurate wind climatology up to 200 m above sea level.
For the wind turbine locations, wind speed data at the nearest KNW-grid
point were used. The wind speed at hub height was calculated by a
linear interpolation of KNW-levels to the hub height. This wind speed
was then used to calculate the average yearly power output for each
wind turbine location over the full period of 35 years.
Statistical
Analysis
Technology versus Climatology
In the reference situation,
the turbines’ GPBTs were calculated using the high-resolution
data from the KNW-Atlas (2.5 by 2.5 km grid, hourly data). To assess
the importance of knowing the location-specific turbine size and wind
climatology, this reference was compared to the turbines’ GPBTs
for four scenarios in which variability characteristics were modified:The importance of
spatial variability
in the GPBT calculations was assessed by using a spatial average of the wind data.The importance of temporal variability
was assessed by using a temporal average of the wind
data.The importance
of spatial and temporal
variability was assessed using a spatial and temporal average of the wind data.The importance of technological variation
was assessed using average turbine sizes for on- and
offshore turbines.Spatial average means
that for every hour in the 35-year
study period, the wind data of each grid point were averaged and used
as wind speed value at that hour for every grid point in the domain
prior to calculating the power output for that hour. Similarly, a
temporal average means that all hourly wind speed values at a certain
grid point were averaged and used for every time slot at that location.
Using both the spatial and the temporal average, only one wind speed
value was used for all turbines for the whole study period, resulting
in only the technological variability of the wind turbines (e.g.,
hub height, diameter, and cut-in and cut-out wind speeds) remaining.
Lastly, technological averages were created by using average onshore
and offshore turbine characteristics based on the turbines in the
study area, which are shown in Figure .Box plots show the distribution
of important technological wind
turbine characteristics for the turbines in the data set. Blue bars
are onshore turbines (n = 4061), and green bars are
offshore turbines (n = 80). The plots show the three
quartile values of the distribution, the 1.5 interquartile range represented
by the whiskers, and the data points outside this range as individual
values. The red dots represent the mean used for average turbine sizes.The Kling–Gupta efficiency
(KGE) was used to calculate the
effect of neglecting spatial, temporal, or technological variability.
The KGE is a combination of correlation, bias, and variability between
scenario n (constant wind in space, time, or both
or constant turbine type) and the reference scenario and is defined
as[42]with r the Pearson correlation coefficient
between the GPBT, γ the variability
ratio ((σ/μ)·(μ/σ)),
and β the bias ratio (μ/μ), with
σ the standard deviation and μ the mean of the GPBT results,
of scenario n (see above) compared to the reference
scenario with a 2.5 by 2.5 km grid, hourly wind speed data, and turbine-specific
data. The KGE ranges from −∞ to 1 (1 being a perfect
fit).
Importance of Spatial and Temporal Resolution
The importance
of using a high spatial and temporal resolution in the GPBT calculations
was investigated as well, because wind data on large spatial scales
are usually available at coarser resolutions than used in this study.[43,44] For this, 25 data sets were created from the KNW-Atlas data by aggregating
temporal and spatial resolutions to a coarser scale, based on typical
resolutions of regional and global climate archives:[45]temporal resolution:
1 h (default), 3 h, 6 h, 12 h,
and 24 hspatial resolution: 2.5 by 2.5
km (default), 5 by 5
km, 10 by 10 km, 30 by 30 km, and 80 by 80 kmReduction of temporal and spatial resolutions was obtained
by subsampling the default data at indicated space and time intervals.
Daily wind speed data were constructed by sampling data at noon (12:00
UTC). GPBTs of the 4161 wind power locations were recalculated for
the 25 additional data sets, and the results of each data set were
evaluated against the reference data set using the KGE (see eq ). All spatiotemporal analyses
were carried out using NCL.[46]
Results
Regression
Model
The optimal AIC model fit to describe
turbine life cycle GHG emission as a function of its diameter (D), hub height (h), and onshore/offshore
technology indicator (T) waswhere c0 = 2.00[±0.45]
is the intercept, c1 = 1.27[±0.50], c2 = 0.84[±0.56], and c3 = 0.29[±0.10]. Figure shows the regression lines for offshore
and onshore wind turbines based on 28 LCA studies found in the literature.[8−12,21−32]
Figure 3
GHG
emissions of onshore turbines (T = 0, gray
line shading) and offshore turbines (T = 1, purple
line shading) as a function of log(D·h). The shading represents the 95% confidence interval.
The markers are the harmonized LCA results from the literature (circles
are onshore and triangles offshore wind turbines).
GHG
emissions of onshore turbines (T = 0, gray
line shading) and offshore turbines (T = 1, purple
line shading) as a function of log(D·h). The shading represents the 95% confidence interval.
The markers are the harmonized LCA results from the literature (circles
are onshore and triangles offshore wind turbines).
Reference Situation
Using the turbine-specific
GHG
emissions and wind data from the KNW-Atlas at the highest spatiotemporal
resolution, GPBTs show a pronounced spatial pattern (Figure ). The lowest values are located
offshore and close to the coast (1.8 months as lowest GPBT), where
wind speeds tend to be higher. Inland, where lower wind speeds prevail,
the GPBT is typically higher (up to 22.5 months). The average GPBT
for wind turbines in northwestern Europe is 5.25 months.
Figure 4
Greenhouse
gas payback time (in months) for the reference situation
(wind data at 2.5 by 2.5 km and hourly resolution and turbine-specific
size characteristics).[46]
Greenhouse
gas payback time (in months) for the reference situation
(wind data at 2.5 by 2.5 km and hourly resolution and turbine-specific
size characteristics).[46]
Ignoring Variability in Wind Speed and Turbine
Size
Spatially averaging wind speed while maintaining the
hourly temporal
resolution and the variation in turbine technology results in a poor
match with the reference data (KGE = −0.27) (Figure a). This is due to a 2-fold
underestimation of the GPBT (β = 1.93), while the spread in
the GPBT is smaller than in the reference situation (γ = 0.27).
The correlation between GPBTs of the spatially averaged wind speed
and the reference situation is also relatively low (r = 0.53).
Figure 5
Comparison of greenhouse gas payback times (GPBT) for the reference
scenario vs the scenarios with spatially averaged wind speed (a),
time-averaged wind speed (b), wind speed averaged over space and time
(c), and average turbine size for onshore and offshore farms (d).
Offshore wind locations are represented by the blue dots, and onshore
wind locations are represented by the black crosses. KGE is the Kling–Gupta
efficiency, r the Pearson correlation coefficient,
γ the variability ratio, and β the bias ratio.[46]
Comparison of greenhouse gas payback times (GPBT) for the reference
scenario vs the scenarios with spatially averaged wind speed (a),
time-averaged wind speed (b), wind speed averaged over space and time
(c), and average turbine size for onshore and offshore farms (d).
Offshore wind locations are represented by the blue dots, and onshore
wind locations are represented by the black crosses. KGE is the Kling–Gupta
efficiency, r the Pearson correlation coefficient,
γ the variability ratio, and β the bias ratio.[46]Using a time-averaged wind speed at a 2.5 by 2.5 km spatial
resolution
results in an even poorer match with the reference data with a KGE
of −0.53 (Figure b). This low KGE value is mainly due to a large overestimation of
the spread in GPBT (γ = 2.51). Averaging wind speed both spatially
and temporally also gives a negative KGE of −0.26 (Figure c). Similar to the
spatially homogeneous wind field, the average GPBT is strongly overestimated
(β = 1.94).Using an average turbine size for on- and
offshore wind turbines
results in a much higher KGE of 0.82 (Figure d), compared to neglecting climatological
variability. The correlation coefficient is relatively high (r = 0.88), and systematic deviations of the mean and spread
are relatively small (β = 1.12; γ = 1.06).
Spatial and
Temporal Resolution
Figure summarizes the influence of the spatial
and temporal resolution on the KGE performance metric and its components. Figure a shows that decreasing
the spatial resolution is the dominant factor for lowering the KGE,
while temporal resolution (hourly vs daily wind speed estimations)
has only a limited influence on the KGE. The lowest KGE is found for
the spatial resolution of 80 by 80 km (KGE = 0.18–0.43). The
30 by 30 km resolution provides intermediate KGEs (0.65–0.75),
while a 10 by 10 km resolution or higher always results in a KGE greater
than 0.89. The relatively low KGE for the 80 by 80 km resolution is
caused by an overestimation of the spread in GPBT (γ = 1.48–1.75; Figure c) in combination
with a decrease in the correlation coefficient (r = 0.79–0.81; Figure d). The γ coefficient shows two interesting trends:
it decreases with a decrease in temporal resolution, and it increases
with a decrease in spatial resolution. These two trends counteract
one another resulting in a higher KGE for the 80 by 80 km resolution
with the lowest temporal resolution (24 hly).
Figure 6
Kling–Gupta efficiency
(a), Pearson correlation coefficient
(b), variability ratio (c), and bias ratio (d) of the GPBT at various
coarser spatial (5 by 5, 10 by 10, 30 by 30, and 80 by 80 km) and
temporal resolutions (3, 6, 12, 24 hly) relative to the most detailed
reference resolution (resKNW: hourly and 2.5 by 2.5 km).[46]
Kling–Gupta efficiency
(a), Pearson correlation coefficient
(b), variability ratio (c), and bias ratio (d) of the GPBT at various
coarser spatial (5 by 5, 10 by 10, 30 by 30, and 80 by 80 km) and
temporal resolutions (3, 6, 12, 24 hly) relative to the most detailed
reference resolution (resKNW: hourly and 2.5 by 2.5 km).[46]
Discussion
Interpretation
The analysis showed
that the spatial
and temporal wind information are of particular importance when assessing
the wind turbine greenhouse gas payback time, a fact that is often
neglected in LCAs, while the variation in turbine size appears to
be of relatively lower importance. The analysis further indicated
that daily wind speed data on a 30 by 30 km grid provide results that
still match the reference high-resolution data (KGE = 0.75), although
a spatial resolution of 10 by 10 km would further improve model performance
(KGE = 0.89).When time-averaged wind speeds over 35 years were
used as an extreme scenario, GPBTs were severely overestimated. Wind
speed shows a non-normal temporal frequency distribution, with lower
wind speeds occurring more frequently than higher values.[35] Combined with the nonlinear dependence of the
power output on the wind speed, the long-term average wind speed causes
a strong underestimation of the power output and hence an overestimation
of the GPBT. Using one daily wind speed value measured at noon performed
equally well compared to the use of hourly data. In Europe, the average
wind speed at noon is slightly higher than the daily mean for vertical
levels up to 80 m.[47] Because more than
75% of the wind turbines included here have hub heights lower than
80 m, this leads to slightly higher power yields and consequently
a 10% underestimation of GPBT compared to using the daily averaged
wind data.Completely neglecting spatial variability in the
wind speed led
to large over- and underestimations of GPBT of individual wind turbines.
Although offshore wind turbines require more building materials (and
hence have higher GHG emissions) than onshore installations, offshore
GPBT are typically lower because of the higher wind speeds over sea.
The results reflect, however, only a relatively small sample of only
80 offshore wind turbine locations; more offshore locations should
be included to consolidate this conclusion.
Uncertainties
This study showed that it is highly relevant
to account for spatiotemporal and technological variation when calculating
the GPBT of wind electricity. A number of uncertainties may, however,
influence the results, which are further discussed below.First,
wind farms were treated as a single geographical location, while in
reality wind farms may occupy large surface areas. The largest farm
in the data set (175 turbines with a diameter of 107 m) covers an
area of approximately 56 km2, thus covering multiple grid
cells in the KNW-Atlas, which could each have a distinct wind climatology.
However, less than 2% of the wind turbine locations in the data set
span more than one grid cell and less than 0.6% more than two grid
cells. Additionally, large wind farms are predominantly located offshore,
where wind climatology is more stable because of low surface roughness.[35] Therefore, the effect of ignoring the spatial
extent of wind farms is considered limited in the context of this
study.The power performance of wind turbines can also be influenced
by
wake effects. In a wind farm, downstream turbines are affected by
a decrease in wind speed due to momentum loss caused by upstream turbines.[48] Several studies[35,49] report that
power output in wind farms are typically 5 to 10% lower because of
these wake effects, but losses could be as high as 50% in large farms
with narrow turbine spacing.[50] Here, more
than 75% of the locations consisted of fewer than 4 turbines and only
0.1% of the locations had array sizes exceeding 10 × 10 turbines.
Wake effects therefore are unlikely to influence the GPBT calculations.
Still, wake effects may become important for other locations in the
world and as more large wind farms are built in the future.Another source of uncertainty is that a resolution of 2.5 km is
most likely not sufficient to capture the local properties of wind
speed at the top of mountain ranges. The energy yield of a wind turbine
at mountain tops is therefore most likely underestimated in this analysis.
However, with increasing height the air density decreases, which also
influences power performance. A recent study by Jung and Schindler[51] showed that at a height of 800 m, the highest
elevation with wind turbines in the study area, annual energy yields
are overestimated by 6% when changes in air density are not considered.
The same error in GPBTs is achieved when taking one daily wind speed
measure instead of hourly data or changing from a 2.5 by 2.5 km to
a 5 by 5km grid. While the uncertainty from this simplification is
not negligible, the 6% error in GPBT from neglecting air density changes
is relatively small compared to the error introduced by using average
wind speeds, as shown in the analysis. In areas with even higher elevations,
spatiotemporal variance in air density should be accounted for because
errors in energy yield can otherwise amount to up to 25%.Incorporating
more turbine-specific losses can further improve
the GPBT calculations. Examples are performance decline due to aging,
which has been reported to lie around 0.6% per year,[52] and losses due to rotor blade soiling and/or icing, which
are generally assumed to account for 2%, but can in rare cases exceed
20%.[53]Finally, a gas-fired power
plant was chosen as the background energy
system to focus the investigation on the effect of changes in wind
climatology and turbine technology. More advanced reference systems
that more precisely reflect what is replaced by the produced wind
electricity can also be considered, but that would require a substantial
amount of extra information about the electricity system as a whole.[54] Another possibility to evaluate the environmental
trade offs of wind electricity is to integrate the location-specific
long-term power output and material requirements for wind turbines
into integrated assessment models.[55]
Outlook
The method presented here can be used to derive
the environmental performance of current and future individual wind
turbines worldwide even when limited information on turbine technology
is available. Following the developments in the wind energy market
to build larger wind farms, wake effects should be included in the
future, and when areas with higher elevation are considered, the spatiotemporal
variability in air density has to be considered.Recent studies
specifically focused on the energy production potential of wind turbines
but did not consider environmental impacts such as GPBT[43,56,57] or use wind climatology that
is either not globally available or at coarser resolutions. This study
indicates that the use of current spatial resolution for global climate
data archives (e.g., ERA-Interim[37]) of
80 by 80 km introduces a relatively large uncertainty in the power
predictions (KGE = 0.18–0.43). A new ERA-suite, ERA5,[58] is under development with global climatological
data at an hourly and 30 by 30 km resolution at which the KGE exceeds
0.7.Therefore, using this method with the new ERA-suite would
provide
a good opportunity for location-specific predictions of the environmental
impacts for wind turbines at the global scale. The method may also
be used to identify optimal locations for wind turbines taking into
account environmental impacts. The results could be incorporated as
an extra factor in wind energy potential studies for various regions
worldwide. In addition to the GPBT, this method can also be used to
calculate payback times for other environmental impacts, such as water
and mineral resource scarcity,[59,60] giving a more complete
picture of wind turbines’ environmental performances.This study showed that the GPBT of wind turbines in northwestern
Europe varies between 1.8 and 22.5 months. Detailed spatiotemporal
(at least daily wind speed on a 30 by 30 km grid) wind climatology
as well as hub height and rotor diameter of the wind turbines are
required to assess the greenhouse gas payback times of wind electricity
with sufficient accuracy. The findings imply that a location-specific
assessment of wind turbines’ GPBTs at the global scale is well
within reach with the availability of high-resolution reanalysis data
sets and wind turbine databases.
Authors: Simon P Gaultier; Anna S Blomberg; Asko Ijäs; Ville Vasko; Eero J Vesterinen; Jon E Brommer; Thomas M Lilley Journal: Environ Sci Technol Date: 2020-08-24 Impact factor: 9.028