| Literature DB >> 31257375 |
Zhen Yang1, Yujing Guo1, Rene M Koenigs1.
Abstract
Benzyl thioethers undergo rhodium(ii) catalyzed sigmatropic rearrangement reactions with aryldiazoacetates. Depending on the solvent and the electronic properties of the sulfide, the intermediate ylide undergoes either [1,2]- or [2,3]-sigmatropic rearrangement reactions in high yields.Entities:
Year: 2019 PMID： 31257375 DOI： 10.1039/c9cc03809d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222