Unintentional persistent organic pollutants in cement kilns co-processing solid wastes.

Co-processing solid waste in cement kilns has become increasingly widespread in recent years. Persistent organic pollutants (POPs) can be unintentionally produced and emitted from cement kilns, especially kilns in which solid waste is co-processed. Unintentionally produced POP formation and emission by cement kilns co-processing solid waste therefore need to be studied in detail to allow the potential risks posed by cement kiln co-processing techniques to be assessed. Many field studies and laboratory simulation experiments have been performed to investigate the formation and release of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). However, the formations, characteristics and emission factors of various emerging unintentionally produced POPs have not been comprehensively reviewed. Here, emissions of well-known unintentionally produced POPs (PCDD/Fs and polychlorinated biphenyls) and emerging unintentionally produced dioxin-like POPs (polybrominated dibenzo-p-dioxins and dibenzofurans, polychlorinated naphthalenes, and chlorinated and brominated polycyclic aromatic hydrocarbons) in cement kilns co-processing solid waste are reviewed, focusing on formations and influencing factors of those unintentional POPs. Data from field studies indicated that the main stages in which POPs are unintentionally produced in cement kilns co-processing solid waste are the cyclone preheater outlet, suspension preheater boiler, humidifier tower, and back-end bag filter. The raw material composition, chlorine and bromine contents, and temperature are the most important factors affecting POP formation. The homolog distributions and congener profiles of POPs formed unintentionally in cement kilns were compared, and it was found that larger amounts of less-chlorinated homologs than more-chlorinated homologs are emitted. Emission factors for various unintentionally produced POPs for cement kilns co-processing solid waste were summarized, and could be useful for compiling global emission inventories for pollutants covered by the Stockholm Convention. This comprehensive review improves our understanding of unintentional production and emissions of POPs by cement kilns co-processing solid waste.