Literature DB >> 31247822

Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands.

Yuya Ashida, Kazuya Arashiba, Hiromasa Tanaka1, Akihito Egi2, Kazunari Nakajima, Kazunari Yoshizawa2, Yoshiaki Nishibayashi.   

Abstract

We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and 1,5-bis(diphenylphosphino)pentane worked effectively toward ammonia formation.

Entities:  

Year:  2019        PMID: 31247822     DOI: 10.1021/acs.inorgchem.9b01340

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  3 in total

1.  Relating N-H Bond Strengths to the Overpotential for Catalytic Nitrogen Fixation.

Authors:  Matthew J Chalkley; Jonas C Peters
Journal:  Eur J Inorg Chem       Date:  2020-04-09       Impact factor: 2.524

2.  Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site.

Authors:  Amy L Speelman; Ilija Čorić; Casey Van Stappen; Serena DeBeer; Brandon Q Mercado; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2019-08-12       Impact factor: 15.419

3.  A Chatt-Type Catalyst with One Coordination Site for Dinitrogen Reduction to Ammonia.

Authors:  Tobias A Engesser; Andrei Kindjajev; Jannik Junge; Jan Krahmer; Felix Tuczek
Journal:  Chemistry       Date:  2020-10-19       Impact factor: 5.236

  3 in total

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