| Literature DB >> 31241967 |
Shi-Chao Lu1, Yu-Yan Liang1, Liang Li1, Xiao-Lei Wang1, Shi-Peng Zhang1, Ya-Ling Gong1, Shu Xu1.
Abstract
A concise synthesis of the tricyclo[4.3.1.03,7]decane caged core of palhinine alkaloids was developed with SmI2-mediated cyclization and light-initiated radical addition-fragmentation as key steps. Compared with the reported racemic routes which are all based on Diels-Alder-type key reactions, our strategy would be more readily accessible to the asymmetric total syntheses of the palhinine alkaloids.Entities:
Year: 2019 PMID： 31241967 DOI： 10.1021/acs.orglett.9b01898
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005