| Literature DB >> 31215555 |
Mayu Fukuda1, Rafael Rodríguez, Zulema Fernández, Tatsuya Nishimura, Daisuke Hirose, Go Watanabe, Emilio Quiñoá, Félix Freire, Katsuhiro Maeda.
Abstract
The introduction of a single chiral substituent with a switchable conformer equilibrium at the poly(phenyl isocyanate) terminus allowed the control of the helical sense of the polymer backbone using various external stimuli. Helical sense enhancement was achieved through a domino effect, where the helical sense was assigned by VCD spectroscopy and DFT calculations.Entities:
Year: 2019 PMID： 31215555 DOI： 10.1039/c9cc03555a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222