Literature DB >> 31211451

β-CsB9 O14 : A Triple-Layered Borate with Edge-Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence.

Shujuan Han1, Chunmei Huang1,2, Abudukadi Tudi1,2, Shuaishuai Hu1,2, Zhihua Yang1, Shilie Pan1.   

Abstract

The first triple-layered borate with edge-sharing BO4 tetrahedra, β-CsB9 O14 was obtained under vacuum-sealed condition. It represents a new structure type and enriches the structural diversity of borates. Moreover, β-CsB9 O14 exhibits a short UV cutoff edge and a large birefringence, indicating that it could be regarded as a DUV birefringent crystal.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  deep-ultraviolet; edge-sharing BO4; large birefringence; theoretical calculation; triple-layered borate

Year:  2019        PMID: 31211451     DOI: 10.1002/chem.201902527

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  1 in total

1.  Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence.

Authors:  Mukeremu Aibibula; Li Wang; Shuzhao Huang
Journal:  ACS Omega       Date:  2019-12-13
  1 in total

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