| Literature DB >> 31204737 |
Mohammed A Bahili1, Emily C Stokes2, Robert C Amesbury2, Darren M C Ould2, Bashar Christo2, Rhian J Horne2, Benson M Kariuki2, Jack A Stewart2, Rebekah L Taylor2, P Andrew Williams2, Matthew D Jones3, Kenneth D M Harris2, Benjamin D Ward2.
Abstract
Main-group metals are inherently labile, hindering their use in catalysis. We exploit this lability in the synthesis of isocyanurates. For the first time we report a highly active catalyst that trimerizes alkyl, allyl and aryl isocyanates, and di-isocyanates, with low catalyst loadings under mild conditions, using a hemi-labile aluminium-pyridyl-bis(iminophenolate) complex.Entities:
Year: 2019 PMID： 31204737 DOI： 10.1039/c9cc03339d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222