| Literature DB >> 31204734 |
Paul S Donnelly1, Andrea J North1, Natalia Caren Radjah1, Michael Ricca1, Angus Robertson1, Jonathan M White1, Mark A Rizzacasa1.
Abstract
Two cis-β-MnIIISALPN catalysts were synthesised and tested in the Mukaiyama-Isayama hydration of α,β-unsaturated esters. The MnIIIEtOSALPN(acac) complex 7 is the most active and catalyses hydration with little or no detectable undesired alkene reduction. This catalyst is superior for alkene hydration compared to the originally reported Mn(dpm)3 catalyst.Entities:
Year: 2019 PMID： 31204734 DOI： 10.1039/c9cc03921j
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222