| Literature DB >> 31198915 |
Omar Padilla-Vélez1, Kyle S O'Connor, Anne M LaPointe, Samantha N MacMillan, Geoffrey W Coates.
Abstract
Design and synthesis of a Ni(ii) "sandwich" α-diimine complex (1) resulted in a switchable catalyst for the living polymerisation of ethylene over a range of temperatures and pressures. Varying these conditions produced a well-defined tetrablock copolymer comprising branched and highly linear polyethylenes. This copolymer improved the toughness of a phase separated LDPE/HDPE blend by nonreactive interfacial compatibilisation.Entities:
Year: 2019 PMID： 31198915 DOI： 10.1039/c9cc03154e
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222