| Literature DB >> 31190446 |
Conrad A P Goodwin1, Jing Su2, Thomas E Albrecht-Schmitt3, Anastasia V Blake1,4, Enrique R Batista2, Scott R Daly4, Stefanie Dehnen5, William J Evans6, Andrew J Gaunt1, Stosh A Kozimor1, Niels Lichtenberger1,5, Brian L Scott7, Ping Yang2.
Abstract
We report the small-scale synthesis, isolated yield, single-crystal X-ray structure, 1 H NMR solution spectroscopy /solid-state UV/Vis-nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am3+ organometallic complex, [Am(C5 Me4 H)3 ] (1). This constitutes the first quantitative data on Am-C bonding in a molecular species.Entities:
Keywords: actinides; americium; cyclopentadienyl ligands; organometallic complexes; structure elucidation
Year: 2019 PMID： 31190446 DOI： 10.1002/anie.201905225
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336