High Energy Capacitors Based on All Metal-Organic Frameworks Derivatives and Solar-Charging Station Application.

High energy and efficient solar charging stations using electrochemical capacitors (ECs) are a promising portable power source for the future. In this work, two kinds of metal-organic framework (MOF) derivatives, NiO/Co3 O4 microcubes and Fe2 O3 microleaves, are prepared via thermal treatment and assembled into electrochemical capacitors, which deliver a relatively high specific energy density of 46 Wh kg-1 at 690 W kg-1 . In addition, a solar-charging power system consisting of the electrochemical capacitors and monocrystalline silicon plates is fabricated and a motor fan or 25 LEDs for 5 and 30 min, respectively, is powered. This work not only adds two novel materials to the growing categories of MOF-derived advanced materials, but also successfully achieves an efficient solar-ECs system for the first time based on all MOF derivatives, which has a certain reference for developing efficient solar-charge systems.