Literature DB >> 31184174

Carboallylation of Electron-Deficient Alkenes with Organoboron Compounds and Allylic Carbonates by Cooperative Palladium/Copper Catalysis.

Kazuhiko Semba1, Naoki Ohta1, Yoshiaki Nakao1.   

Abstract

The aryl- and alkylallylation of electron-deficient alkenes was achieved by cooperative palladium/copper catalysis. The reaction affords various carbon skeletons from readily available alkenes, allylic carbonates, and organoboron compounds, whereby a variety of functional groups such as acetyl, alkoxycarbonyl, bromo, and cyano moieties are tolerated well.

Entities:  

Year:  2019        PMID： 31184174     DOI： 10.1021/acs.orglett.9b00915

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  9 in total

1.  Nickel-Catalyzed α-Carbonylalkylarylation of Vinylarenes: Expedient Access to γ,γ-Diarylcarbonyl and Aryltetralone Derivatives.

Authors:  Shekhar Kc; Roshan K Dhungana; Namrata Khanal; Ramesh Giri
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-19       Impact factor: 15.336

2.  Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters.

Authors:  Connor P Delaney; Vincent M Kassel; Scott E Denmark
Journal:  ACS Catal       Date:  2019-12-02       Impact factor: 13.084

3.  Ni-Catalyzed Arylbenzylation of Alkenylarenes: Kinetic Studies Reveal Autocatalysis by ZnX2 *.

Authors:  Roshan K Dhungana; Rishi R Sapkota; Laura M Wickham; Doleshwar Niroula; Bijay Shrestha; Ramesh Giri
Journal:  Angew Chem Int Ed Engl       Date:  2021-09-15       Impact factor: 16.823

4.  Integrating Allyl Electrophiles into Nickel-Catalyzed Conjunctive Cross-Coupling.

Authors:  Van T Tran; Zi-Qi Li; Timothy J Gallagher; Joseph Derosa; Peng Liu; Keary M Engle
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-13       Impact factor: 15.336

5.  Ni-Catalyzed Regioselective 1,2-Dialkylation of Alkenes Enabled by the Formation of Two C(sp3)-C(sp3) Bonds.

Authors:  Roshan K Dhungana; Rishi R Sapkota; Laura M Wickham; Doleshwar Niroula; Ramesh Giri
Journal:  J Am Chem Soc       Date:  2020-12-03       Impact factor: 15.419

6.  Nickel-catalyzed asymmetric reductive aryl-allylation of unactivated alkenes.

Authors:  Zhiyang Lin; Youxiang Jin; Weitao Hu; Chuan Wang
Journal:  Chem Sci       Date:  2021-04-09       Impact factor: 9.825

7.  Nickel-Catalyzed Regioselective Alkenylarylation of γ,δ-Alkenyl Ketones via Carbonyl Coordination.

Authors:  Roshan K Dhungana; Vivek Aryal; Doleshwar Niroula; Rishi R Sapkota; Margaret G Lakomy; Ramesh Giri
Journal:  Angew Chem Int Ed Engl       Date:  2021-07-20       Impact factor: 16.823

8.  Cyclic (Alkyl)(amino)carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes*.

Authors:  Yang Gao; Sima Yazdani; Aaron Kendrick; Glen P Junor; Taeho Kang; Douglas B Grotjahn; Guy Bertrand; Rodolphe Jazzar; Keary M Engle
Journal:  Angew Chem Int Ed Engl       Date:  2021-07-29       Impact factor: 16.823

9.  Photoinduced 1,2-dicarbofunctionalization of alkenes with organotrifluoroborate nucleophiles via radical/polar crossover.

Authors:  María Jesús Cabrera-Afonso; Anasheh Sookezian; Shorouk O Badir; Mirna El Khatib; Gary A Molander
Journal:  Chem Sci       Date:  2021-06-07       Impact factor: 9.969
  9 in total

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