The chemistry of guanidinate complexes of the platinum group metals.

In this Perspective article, recent advances in the chemistry of platinum group metal complexes containing mono- and dianionic guanidinate ligands, i.e. [(RN)2C-NR2]- and [(RN)2C[double bond, length as m-dash]NR]2-, respectively, are presented. Synthetic and structural aspects, reactivity studies, and applications of these compounds are discussed.