Literature DB >> 31119222

A general and practical Ni-catalyzed C-H perfluoroalkylation of (hetero)arenes.

Shaoke Zhang1, Nicolas Rotta-Loria, Florian Weniger, Jabor Rabeah, Helfried Neumann, Christoph Taeschler, Matthias Beller.   

Abstract

A direct perfluoroalkylation of (hetero)arenes using the air- and moisture-stable complex (dppf)Ni(o-tol)Cl was developed (23 examples). The novel procedure allows for the synthesis of various fluorinated products and tolerates sensitive functional groups including aldehydes, free amino groups and several heterocycles.

Entities:  

Year:  2019        PMID: 31119222     DOI: 10.1039/c9cc01971e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Ruthenium-Catalyzed Site-Selective Trifluoromethylations and (Per)Fluoroalkylations of Anilines and Indoles.

Authors:  Yang Li; Helfried Neumann; Matthias Beller
Journal:  Chemistry       Date:  2020-05-12       Impact factor: 5.236

  1 in total

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