Literature DB >> 31117700

Silver-Catalyzed anti-Markovnikov Hydroboration of C-C Multiple Bonds.

Yan Wang1,2, Rui Guan1,2, Paramasivam Sivaguru2, Xuefeng Cong2, Xihe Bi2.   

Abstract

A simple silver salt (AgOAc)-catalyzed anti-Markovnikov-selective hydroboration of alkenes, 1,3-dienes, and alkynes with pinacolborane (HBpin) has been described. This strategy provides an efficient and practical method to access various alkyl-, allyl-, and ( E)-alkenylboronate esters in good to excellent yields with regio- and stereoselectivity under ligand- and base-free conditions.

Entities:  

Year:  2019        PMID: 31117700     DOI: 10.1021/acs.orglett.9b01217

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  5 in total

Review 1.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

2.  Solvent-free hydroboration of alkynes catalyzed by an NHC-cobalt complex.

Authors:  Małgorzata Bołt; Patrycja Żak
Journal:  RSC Adv       Date:  2022-06-27       Impact factor: 4.036

3.  Cyclic (Alkyl)(amino)carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes*.

Authors:  Yang Gao; Sima Yazdani; Aaron Kendrick; Glen P Junor; Taeho Kang; Douglas B Grotjahn; Guy Bertrand; Rodolphe Jazzar; Keary M Engle
Journal:  Angew Chem Int Ed Engl       Date:  2021-07-29       Impact factor: 16.823

4.  C-Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3-Enynes.

Authors:  Ziyong Wang; Jason Wu; Walid Lamine; Bo Li; Jean-Marc Sotiropoulos; Anna Chrostowska; Karinne Miqueu; Shih-Yuan Liu
Journal:  Angew Chem Int Ed Engl       Date:  2021-08-31       Impact factor: 16.823

Review 5.  Petasis vs. Strecker Amino Acid Synthesis: Convergence, Divergence and Opportunities in Organic Synthesis.

Authors:  Wayiza Masamba
Journal:  Molecules       Date:  2021-03-18       Impact factor: 4.411

  5 in total

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