Thermal and thermo-oxidative degradation kinetics and characteristics of poly (lactic acid) and its composites.

Thermal degradation behavior and kinetics of starch/PLA composites in an inert and oxygen atmosphere were investigated by TG and TG-FTIR techniques. It is shown that the thermal degradation process can be divided into three stages, and a significant difference between thermal and thermo-oxidative degradation is the third stage in which the residual chars are further cracked for the thermo-oxidative degradation. The activation energy was calculated using the iso-conversional Flynn-Wall-Ozawa (FWO) method. The lower activation energy for thermo-oxidative degradation indicated that oxygen had an accelerated effect on thermal degradation. The variation of activation energy indicated that the decomposition of all the samples was a complex process that included at least two different mechanisms. Evolution of the evolved gaseous products with temperature was studied to understand the thermal and thermo-oxidative decomposition comprehensively. According to the TG-FTIR analysis, the gaseous products mainly contained lactide, cyclic oligomers, aldehydes, CO2, CO, and H2O.