| Literature DB >> 31095805 |
Yulia Y Enakieva1, Anna A Sinelshchikova1, Mikhail S Grigoriev1, Vladimir V Chernyshev1,2, Konstantin A Kovalenko3,4, Irina A Stenina5, Andrey B Yaroslavtsev5, Yulia G Gorbunova1,5, Aslan Y Tsivadze1,5.
Abstract
The design of new solid-state proton-conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF (IPCE-1Ni), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55×10-3 S cm-1 at 75 °C and 80 % relative humidity).Entities:
Keywords: conducting materials; metal-organic frameworks; porous materials; porphyrinylphosphonates; proton conductivity
Year: 2019 PMID： 31095805 DOI： 10.1002/chem.201902212
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236