Regioselective Functionalization of Stable BN-Modified Luminescent Tetraphenes for High-Resolution Fingerprint Imaging.

A series of novel BN tetraphene derivatives have been prepared successfully for the first time via a post-functionalization strategy. The optical and electronic properties of these derivatives could be tuned systematically by the incorporation of different substituents on the main skeleton. The functionalized BN-containing luminogens have been explored for the detection of latent fingerprints (LFPs) on different substrates, including glass, aluminum foil, plastic, and ironware. This strategy provides great versatility in LFP imaging and good potential in elucidating the chemical information within LFPs, making the strategy valuable in forensic investigations.