Natural attenuation mechanism and health risk assessment of 1,1,2-trichloroethane in contaminated groundwater.

1,1,2-trichloroethane (TCA) is a contaminant in many pesticide and chemical fields. This study mainly described the potential effectiveness of the natural attenuation of 1,1,2-TCA in groundwater in a typical pesticide-contaminated field in east China. In this study, six typical 1,1,2-TCA-contaminated sites (MW14, MW21, MW25, MW31, MW36 and MW41) were selected, and the field investigation results indicated that there was an obvious decline in the concentrations of 1,1,2-TCA over time in all selected sites. Furthermore, the attenuation rate of 1,1,2-TCA concentration in sites MW14, MW21, MW25, MW31 and MW41 followed the first-order kinetic equation, and the first-order attenuation rate constants were calculated. The health risks of 1,1,2-TCA and its degradation product dichloroethane (DCA) were assessed and compared in site MW14. The result showed that the health risks of 1,1,2-TCA were much higher than those of DCA, and 1,1,2-TCA was the contamination source in this site. 16S rRNA sequencing was also conducted to investigate the diversity of the bacterial community in 1,1,2-trichloroethane (TCA)-contaminated groundwater, and Geobacter, Thauera, Pseudomonas, Diaphorobacter were the main species in the bacterial community.