Synthesis, Structure, and Characterization of Two Mixed-Cation Quaternary Chalcogenides K2BaSnQ4 (Q = S, Se).

Two new isostructural metal chalcogenides, K2BaSnS4 and K2BaSnSe4, have been isolated for the first time. They feature the intriguing ∞ 1[BaSnQ4]2- (Q = S, Se) tunnel structures which are separated by K+ cations. Experiments combined with theoretical calculations demonstrate that K2BaSnS4 possesses a large energy gap (3.09 eV), which is conducive for large laser-induced damage thresholds (LDTs), and maintains a relatively moderate SHG response (0.5 × AgGaS2) in the meanwhile. Moreover, K2BaSnS4 possesses good phase-matchability, which stems from its suitable birefringence (0.04@2.09 μm).