| Literature DB >> 31050160 |
Francesca Liguori1, Pierluigi Barbaro1, Nicola Calisi2,3.
Abstract
The oxidation reaction of 5-hydroxymethylfurfural to the bioplastic monomer 2,5-furandicarboxylic acid over heterogenous resin-supported Pt catalysts was investigated in detail, under continuous flow, base-free conditions, and in neat water. The product was continuously obtained in 99 % yield by running the reaction at 120 °C, 303 s residence time, 1.2 mL min-1 O2 flow rate, and 7.7 bar O2 pressure. The product was isolated with a high space-time-yield of 46.0 g L-1 h-1 without purifications or acid/base treatments.Entities:
Keywords: 2,5-furandicarboxylic acid; continuous flow; green chemistry; heterogeneous catalysis; water chemistry
Year: 2019 PMID： 31050160 DOI： 10.1002/cssc.201900833
Source DB: PubMed Journal: ChemSusChem ISSN： 1864-5631 Impact factor: 8.928