Literature DB >> 31038911

Quinolinylmethanone-Based Thermally Activated Delayed Fluorescence Emitters and the Application in OLEDs: Effect of Intramolecular H-Bonding.

Vasudevan Thangaraji1, Pachaiyappan Rajamalli1, Jayachandran Jayakumar1, Min-Jie Huang1, Yu-Wei Chen1, Chien-Hong Cheng1.   

Abstract

Three new quinoline TADF emitters, 2QPM-mDC, 2QPM-mDTC, and 4QPM-mDTC, were designed and synthesized and the emitters show Δ EST as low as 0.07 eV and high PL quantum yield (PLQY) up to 98%. An electroluminescence device based on 2QPM-mDTC can reach high EQE over 24%. Compared with the reported TADF devices, the device shows narrow emission bandwidth and high color purity. The excellent device performance is likely ascribed to the molecular design of 2QPM-mDTC containing an intramolecular H-bonding in the molecule.

Entities:  

Keywords:  H-bonding; OLEDs; TADF; narrow bandwidth; quinoline

Year:  2019        PMID: 31038911     DOI: 10.1021/acsami.8b22704

Source DB:  PubMed          Journal:  ACS Appl Mater Interfaces        ISSN: 1944-8244            Impact factor:   9.229


  2 in total

1.  Homologation of the Fischer Indolization: A Quinoline Synthesis via Homo-Diaza-Cope Rearrangement.

Authors:  Gabriela Guillermina Gerosa; Sebastian Armin Schwengers; Rajat Maji; Chandra Kanta De; Benjamin List
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-07       Impact factor: 15.336

2.  Intramolecular Hydrogen Bonding in Thermally Activated Delayed Fluorescence Emitters: Is There Evidence Beyond Reasonable Doubt?

Authors:  Matthias Hempe; Nadzeya A Kukhta; Andrew Danos; Andrei S Batsanov; Andrew P Monkman; Martin R Bryce
Journal:  J Phys Chem Lett       Date:  2022-08-25       Impact factor: 6.888

  2 in total

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