Literature DB >> 31020971

Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions.

Ryan J Andrews1, Saurabh S Chitnis, Douglas W Stephan.   

Abstract

The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.

Entities:  

Year:  2019        PMID: 31020971     DOI: 10.1039/c9cc02460c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann-Beckett Method.

Authors:  Philipp Erdmann; Lutz Greb
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-08       Impact factor: 16.823

2.  Tetragonal phosphorus(v) cations as tunable and robust catalytic Lewis acids.

Authors:  James C Gilhula; Alexander T Radosevich
Journal:  Chem Sci       Date:  2019-06-18       Impact factor: 9.825

  2 in total

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