Synergistic Tricolor Emission-Based White Light from Supramolecular Organic-Inorganic Hybrid Gel.

The development of engineered hybrid systems by encapsulating nanoparticles in gel scaffolds and their synergistic effects are highly crucial for the fabrication of advanced functional materials. Herein, a series of dipeptides containing an aromatic amino acid at the N-terminal and an aliphatic amino acid at the C-terminal were synthesized and studied. Among them, only the dipeptide l-Phe-l-Val can form both hydro- and organogelator, depending on the N- and C-terminal protecting groups. The organogel shows bright blue emission under 366 nm UV irradiation; however, the hydrogel does not show such blue emission. Such kind of emission may be due to the self-assembly and high degree of aggregation in the gel state of the phenyl ring. The blue-emitting organogel efficiently encapsulates green emission source CdSe quantum dots and red emission source LD 700 perchlorate dye. The resulting organic-inorganic hybrid gel exhibits white light emission due to the synergistic effect under 366 nm UV irradiation.