Noble Metal Corrosion: Halogen Bonded Iodocarbenium Iodides Dissolve Elemental Gold-Direct Access to Gold-Carbene Complexes.

A common method to dissolve elemental gold involves the combination of an oxidant with a Lewis base that coordinates to the gold surface, thus lowering the metal's redox potential. Herein we report the usage of organic iodide salts, which provide both oxidative power and a coordinating ligand, to dissolve gold under formation of organo-gold complexes. The obtained products were identified as AuIII complexes, all featuring Au-C bonds, as shown by X-ray single-crystal analysis, and can be isolated in good yields. Additionally, our method provides direct access to N-heterocyclic carbene (NHC-type) complexes and avoids costly organometallic precursors. The investigated complexes show dynamic behavior in acetonitrile and in the case of the NHC(-type) complexes, the involved species could be identified as a monocarbene [AuI3 (carbene)] and biscarbene complex [AuI2 (carbene)2 ]+ .