Literature DB >> 30986071

Organocatalytic Synthesis of Sulfoximidoyl-Containing Carbamates from Sulfoximines and Morita-Baylis-Hillman Carbonates.

Zhen Li1, Marcus Frings1, Hao Yu1, Carsten Bolm1.   

Abstract

An unexpected substitution reaction providing sulfoximidoyl-containing carbamates was observed when Morita-Baylis-Hillman carbonates and NH-sulfoximines were mixed in acetonitrile at elevated temperature. Key ingredients were triethylamine and ortho-hydroxybenzoic acid, which both had to be present in catalytic quantities.

Entities:  

Year:  2019        PMID: 30986071     DOI: 10.1021/acs.orglett.9b00772

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Synthesis and Transformations of NH-Sulfoximines.

Authors:  Michael Andresini; Arianna Tota; Leonardo Degennaro; James A Bull; Renzo Luisi
Journal:  Chemistry       Date:  2021-10-13       Impact factor: 5.020

2.  One-Pot Synthesis of N-Iodo Sulfoximines from Sulfides.

Authors:  Anže Zupanc; Marjan Jereb
Journal:  J Org Chem       Date:  2021-03-25       Impact factor: 4.354

  2 in total

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