Literature DB >> 30942222

Successive carbene insertion into 9-phenyl-9-borafluorene.

Tyler A Bartholome1, Kristen R Bluer, Caleb D Martin.   

Abstract

The reactions of 9-phenyl-9-borafluorene with trimethylsilyldiazomethane in a 1 : 1 and 1 : 2 stoichiometry furnished the corresponding BC5 and BC6 heterocycles via the formal insertion of one and two carbene units.

Entities:  

Year:  2019        PMID: 30942222     DOI: 10.1039/c9dt01032g

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  2 in total

1.  The Versatile Reaction Chemistry of an Alpha-Boryl Diazo Compound.

Authors:  Yao Liu; Raimon Puig de la Bellacasa; Bo Li; Ana Belén Cuenca; Shih-Yuan Liu
Journal:  J Am Chem Soc       Date:  2021-08-25       Impact factor: 16.383

2.  Persistent Borafluorene Radicals.

Authors:  Wenlong Yang; Kelsie E Krantz; Lucas A Freeman; Diane A Dickie; Andrew Molino; Gernot Frenking; Sudip Pan; David J D Wilson; Robert J Gilliard
Journal:  Angew Chem Int Ed Engl       Date:  2020-02-03       Impact factor: 15.336

  2 in total

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