Sodium Cobalt Metaphosphate as an Efficient Oxygen Evolution Reaction Catalyst in Alkaline Solution.

Sodium cobalt metaphosphate [NaCo(PO3 )3 ] has CoO octahedra (CoO6 ) and shows superior oxygen evolution reaction (OER) activity in alkaline solution, comparable with the state-of-the-art precious-metal RuO2 catalyst. OER catalysts of this metaphosphate are prepared by combustion (Cb) and solid-state (SS) methods. The combustion-assisted method offers a facile synthesis and one-step carbon composite formation. Unusually high catalytic activity was observed in NCoM-Cb-Ar and could be due to chemical coupling effects between NaCo(PO3 )3 and partially graphitized carbon. This novel electrocatalyst exhibits very small overpotential of 340 mV with high mass activity of 532 A g-1 . Good charge transfer abilities and chemical coupling between NaCo(PO3 )3 and amorphous carbon gives the OER activity in NCoM-Cb-Ar.