Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 A metal- and oxidizing-reagent-free anodic para-selective amination of anilines with phenothiazines.

Literature DB >> 30912541

A metal- and oxidizing-reagent-free anodic para-selective amination of anilines with phenothiazines.

Yan-Chen Wu¹, Shuai-Shuai Jiang, Ren-Jie Song, Jin-Heng Li.

Abstract

A highly para-selective amination of anilines with phenothiazines for producing various functionalized 10-aryl-10H-phenothiazines is reported. The oxidative amination reaction proceeds electrochemically at room temperature, thereby avoiding the use of metals and oxidizing reagents with excellent functional group tolerance and broad substrate scope.

Entities: Chemical

Year: 2019 PMID： 30912541 DOI： 10.1039/c9cc01332f

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

6 in total

Review 1. Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.

Authors: Philip R D Murray; James H Cox; Nicholas D Chiappini; Casey B Roos; Elizabeth A McLoughlin; Benjamin G Hejna; Suong T Nguyen; Hunter H Ripberger; Jacob M Ganley; Elaine Tsui; Nick Y Shin; Brian Koronkiewicz; Guanqi Qiu; Robert R Knowles
Journal: Chem Rev Date: 2021-11-23 Impact factor: 60.622

A metal- and oxidizing-reagent-free anodic para-selective amination of anilines with phenothiazines.

Review 1. Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.

2. Te(II)-Catalyzed Cross-Dehydrogenative Phenothiazination of Anilines.

3. An Air-Stable, Neutral Phenothiazinyl Radical with Substantial Radical Stabilization Energy.

4. Oxidative Dehydrogenation of Hydrazobenzenes toward Azo Compounds Catalyzed by tert-Butyl Nitrite in EtOH.

5. Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings.

6. O₂-Mediated Dehydrogenative Phenoxazination of Phenols.

A metal- and oxidizing-reagent-free anodic para-selective amination of anilines with phenothiazines.

Review 1. Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.

2. Te(II)-Catalyzed Cross-Dehydrogenative Phenothiazination of Anilines.

3. An Air-Stable, Neutral Phenothiazinyl Radical with Substantial Radical Stabilization Energy.

4. Oxidative Dehydrogenation of Hydrazobenzenes toward Azo Compounds Catalyzed by tert-Butyl Nitrite in EtOH.

5. Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings.

6. O2-Mediated Dehydrogenative Phenoxazination of Phenols.

6. O₂-Mediated Dehydrogenative Phenoxazination of Phenols.