Literature DB >> 30912447

Nickel-Catalyzed Carboxylation of Aryl and Heteroaryl Fluorosulfates Using Carbon Dioxide.

Cong Ma1, Chuan-Qi Zhao1, Xue-Tao Xu2, Zhao-Ming Li1, Xiang-Yang Wang2, Kun Zhang2, Tian-Sheng Mei1.   

Abstract

The development of efficient and practical methods to construct carboxylic acids using CO2 as a C1 synthon is of great importance. Nickel-catalyzed carboxylation of aryl fluorosulfates and heteroaryl fluorosulfates with CO2 is described, affording arene carboxylic acids with good to excellent yields under mild conditions. In addition, a one-pot phenol fluorosulfation/carboxylation is developed.

Entities:  

Year:  2019        PMID: 30912447     DOI: 10.1021/acs.orglett.9b00836

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Site-Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO2 F) Enabled by an Air-Stable PdI Dimer.

Authors:  Marvin Mendel; Indrek Kalvet; Daniel Hupperich; Guillaume Magnin; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2019-12-16       Impact factor: 15.336

  1 in total

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