Supercooling Behavior and Dipole-Glass-like Relaxation in a Three-Dimensional Water Framework.

The dynamic behaviors of a new type of three-dimensional (3D) water framework symbiotic with 1D stacking organic guests, including an order-disorder transition of hydrogen atoms, a supercooling phenomenon during phase transition, and a dipole-glass-like relaxation behavior due to locally trapped water molecules, are presented. This extremely scarce 3D water framework, together with the rich dynamic behaviors it exhibits, provides new clues to design new ice-like models for promoting the fundamental understanding of the dynamic behavior of water in diverse solid-states.