Literature DB >> 30899925

Exogenous-oxidant-free electrochemical oxidative C-H phosphonylation with hydrogen evolution.

Yong Yuan1, Jin Qiao, Yangmin Cao, Jingmei Tang, Mengqin Wang, Guojuan Ke, Yichen Lu, Xue Liu, Aiwen Lei.   

Abstract

We herein report a versatile and environmentally friendly electrochemical oxidative C-H phosphonylation protocol. This protocol features a broad substrate scope; not only C(sp2)-H phosphonylation, but also C(sp3)-H phosphonylation is tolerated well under exogenous-oxidant-free and metal catalyst-free electrochemical oxidation conditions.

Entities:  

Year:  2019        PMID： 30899925     DOI： 10.1039/c9cc00975b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Electrochemically driven regioselective C-H phosphorylation of group 8 metallocenes.

Authors:  Hao Zheng; Chang-Hui Liu; Shi-Yu Guo; Gu-Cheng He; Xiang-Ting Min; Bo-Chao Zhou; Ding-Wei Ji; Yan-Cheng Hu; Qing-An Chen
Journal:  Nat Commun       Date:  2022-06-17       Impact factor: 17.694

2.  Direct phosphorylation of benzylic C-H bonds under transition metal-free conditions forming sp3C-P bonds.

Authors:  Qiang Li; Chang-Qiu Zhao; Tieqiao Chen; Li-Biao Han
Journal:  RSC Adv       Date:  2022-06-24       Impact factor: 4.036

3.  Synthesis of Xanthones, Thioxanthones and Acridones by a Metal-Free Photocatalytic Oxidation Using Visible Light and Molecular Oxygen.

Authors:  Alejandro Torregrosa-Chinillach; Rafael Chinchilla
Journal:  Molecules       Date:  2021-02-12       Impact factor: 4.411

4.  Electrochemical C-H phosphorylation of arenes in continuous flow suitable for late-stage functionalization.

Authors:  Hao Long; Chong Huang; Yun-Tao Zheng; Zhao-Yu Li; Liang-Hua Jie; Jinshuai Song; Shaobin Zhu; Hai-Chao Xu
Journal:  Nat Commun       Date:  2021-11-16       Impact factor: 14.919

Review 5.  Recent advances in metal catalyst- and oxidant-free electrochemical C-H bond functionalization of nitrogen-containing heterocycles.

Authors:  Ya-Nan Li; Bin Wang; Ye-Kai Huang; Jin-Song Hu; Jia-Nan Sun
Journal:  Front Chem       Date:  2022-08-19       Impact factor: 5.545
  5 in total

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