Inorganic-Organic Hybrid Janus Fillers for Improving the Thermal Conductivity of Polymer Composites.

Janus fillers represent a combination of inorganic thermally conductive silver nanoparticles and organic polystyrene brushes on one entity but different sides. They are of practical importance for polymer composites with high thermal conductivity because of the improved dispersion and reduced interfacial heat resistance. Moreover, benefiting from the sheetlike structure and single-side deposition of inorganic particles, Janus fillers tend to align such that the heat pathway is constructed in the composite films, when fabricated by layer-by-layer doctor blading. As a result, the in-plane thermal conductivity of the polymer composite is as high as 4.57 W m-1 K-1, with only 10 vol % Janus filler loading.