Literature DB >> 30888189

Iterative Synthesis of Alkenes by Insertion of Lithiated Epoxides into Boronic Esters.

Kevin Bojaryn1, Stefan Fritsch1, Christoph Hirschhäuser1.   

Abstract

The insertion of lithiated epoxides into boronic esters followed by thermal syn-elimination provides a stereospecific entry to alkenes. This process avoids transition metals and is amenable to iteration to provide higher substitution patterns.

Entities:  

Year:  2019        PMID: 30888189     DOI: 10.1021/acs.orglett.9b00517

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Total Synthesis of Resveratrone and iso-Resveratrone.

Authors:  Stefan Fritsch; Nazli Aldemir; Jan Balszuweit; Kevin Bojaryn; Jens Voskuhl; Christoph Hirschhäuser
Journal:  ChemistryOpen       Date:  2022-06-30       Impact factor: 2.630

Review 2.  Transition Metal Catalyst Free Synthesis of Olefins from Organoboron Derivatives.

Authors:  K Bojaryn; C Hirschhäuser
Journal:  Chemistry       Date:  2022-02-28       Impact factor: 5.020

  2 in total

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