Cactus-Inspired Bimetallic Metal-Organic Framework-Derived 1D-2D Hierarchical Co/N-Decorated Carbon Architecture toward Enhanced Electromagnetic Wave Absorbing Performance.

Metal-organic framework (MOF)-derived magnetic metal/carbon nanocomposites have shown tremendous potential for lightweight electromagnetic wave (EMW) absorption. However, it is a challenge but highly significant to design and construct mixed-dimensional hierarchical architectures with synergistically integrated characteristics from individual MOFs for advancing the EMW absorption performance. Inspired by the structure of cactus, a novel hierarchical one-dimensional (1D)-two-dimensional (2D) mixed-dimensional Co/N-decorated carbon architecture comprising carbon nanotubes grafted on carbon flakes (abbreviated as CoNC/CNTs) has been fabricated by the pyrolysis of bimetallic CoZn-ZIF-L. The CoNC/CNTs integrate the advantages of 1D nanotubes for the extra polarization of EMW and 2D nanoflakes with an interconnected porous structure for multiple reflection losses of EMW and optimization of impedance matching. The resultant CoNC/CNTs demonstrate excellent EMW absorbing performance. For the optimal EMW absorbing material of CoNC/CNT-3/1, minimum reflection loss reaches -44.6 dB at 5.20 GHz with a low filler loading of 15 wt %. Moreover, the largest effective bandwidth range achieves 4.5 GHz with a thickness of 1.5 mm and a filled ratio of 20 wt %. These findings indicate that such a mixed 1D-2D hierarchical architecture synergistically enhances EMW absorbing performance. This work sheds light on the rational design of a mixed-dimensional carbon architecture derived from MOFs for desirable functionalities.